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Single electron transfer vs Diels Alder reaction: A comparative study of the reaction of 1-(anthracen-9-yl)-N,N-dimethylmethanamine and (anthracen-9-ylmethyl)(methyl)sulfane with dibenzoylethylene

Tomson Devassia, Jomon P. Jacob, Unnikrishnan A Perupparampil

Abstract


We have examined the reactions of 1-(anthracen-9-yl)-N,N-dimethylmethanamine and (anthracen-9-ylmethyl)(methyl)sulfane with dibenzoylethylene in different solvents. Single electron transfer mediated reactions predominated in the case of 1-(anthracen-9-yl)-N,N-dimethylmethanamine while the Diels-Alder pathway was important for (anthracen-9-ylmethyl)(methyl)sulfane.

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